Search results for " icp"

The geological roots of South America: 4.1 Ga and 3.7 Ga zircon crystals discovered in N.E. Brazil and N.W. Argentina

2015

International audience; We present new LA-ICP-MS in situ geochronological results for seven Eoarchean zircons dated at 3.7 Ga coming from Cretaceous ash layers of NW Argentina and one Hadean single crystal sampled within the São Francisco Craton in NE Brazil. This zircon comprises a zoned magmatic core dated at 4.1 Ga surrounded by a 1.9 Ga overgrowth related to Paleoproterozoic reworking. This Hadean age is consistent with previously published Nd model ages on orthogneisses from the same domain. These two results represent among the oldest geological witnesses discovered to date in South America, which demonstrates the occurrence of a primitive crust. The contrasting age patterns recorded …

Copper supply during the Final Neolithic at the Saint-Blaise/Bains des Dames site (Neuchâtel, Switzerland)

2009

The Saint-Blaise/Bains des Dames stratified site in Neuchâtel, Switzerland, contains several occupations that span the Late through Final Neolithic, including the Horgen, Lüscherz, and Auvernier-Cordé periods. As part of a study on prehistoric metallurgy in western Switzerland, we compare the lead isotope ratios (multicollector inductively coupled plasma mass spectrometer) and elemental compositions (instrumental neutron activation analysis) of the site's numerous copper finds to a database of corresponding measurements for copper ores throughout Europe. The results show a considerable variation in copper compositions present at the site, suggesting complex economic relationships and multip…

Application of LA-ICP-MS as a rapid tool for analysis of elemental impurities in active pharmaceutical ingredients.

2014

The control of inorganic contaminants in active pharmaceutical ingredients has a significant role in the quality control of drug products. The concentration limits for metal residues in drug products have been defined by various regulatory guidelines. Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) is a powerful and fast analytical technique for multi-elemental analysis. A disadvantage in using LA-ICP-MS method is the lack of matrix reference materials for validation and calibration purposes. This article focuses on the handling strategy of laboratory-made matrix calibration standards for the quantification of elemental impurities in an active pharmaceutical ingredie…

Newly discovered orichalcum ingots from Mediterranean sea: Further investigation

2021

Abstract In February 2016, 47 ingots were found in the seabed of Contrada Bulala (Gela, CL, Italy) near the site where 40 ingots had previously been recovered. The ingots composition was determined to be a Cu - Zn alloy, dated by the archaeologist to the VI century B.C. This specific alloy was then known as Orichalcum. From an archaeological point of view, the first question raised about the new discovery was whether the ingots of the first and the second excavations belonged to the same shipwreck. Following the previous study, an elemental analysis was performed on the ingots from the second finding by using ICP-OS and ICP-MS techniques. The chemometric treatment of the analytical results …

XRF and LA-ICP-MS studies of gold and silver artefacts from a 12–13th century CE tumulus in Senegal: Implications for the medieval African gold trade

2019

Abstract Silver and gold artefacts from a 12–13th c. CE tumulus in Senegal were recently analysed by means of XRF and LA-ICP-MS. The identification of major, minor and trace elements allowed gaining a rare insight into the composition of precious metals circulating in that part of Africa in medieval times. The results show that all objects were made of polymetallic alloys. Comparisons with analyses from other West African as well as North African and European silver and gold artefacts suggest that the metal from the studied objects most probably originate from outside West Africa. At least in the case of the gold artefacts, this is quite surprising, as we expected to come across pure West A…

In Situ U‐Th‐Pb Dating and Sr‐Nd Isotope Analysis of Bastnäsite by LA‐(MC)‐ICP‐MS

2019

Bio-char from dead Posidonia oceanica residues as adsorbent towards toxic metal ions

2018

Recently, the pyrolysis of biomass from different algal species and from the Mediterranean sea plant Posidonia oceanica have been proposed for renewable fuel production with a maximum oil yield of 54.97% at 500°C, and high heating values of 24-32 MJ kg-1[1,2]. The pyrolysis produces a large amount of bio-char and the accumulation of this byproduct may cause solid waste pollution problems. Although the composition and properties of bio-char depend on the raw material and on the carbonization process, it is on average composed of amorphous carbon with a highly functionalized surface, which makes it reactive towards inorganic and organic compounds [3]. Considering the reactivity of bio-char, t…

Forensic investigation of brick stones using instrumental neutron activation analysis (INAA), laser ablation-inductively coupled plasma-mass spectrom…

2009

Abstract Brick stones collected from different production facilities were studied for their elemental compositions under forensic aspects using laser ablation–inductively coupled plasma–mass spectrometry (LA–ICP–MS), instrumental neutron activation analysis (INAA) and X-ray fluorescence analysis (XRF). The aim of these examinations was to assess the potential of these methods in forensic comparison analyses of brick stones. The accuracy of the analysis methods was evaluated using NIST standard reference materials (679, 98b and 97b). In order to compare the stones to each other, multivariate data analysis was used. The evaluation of the INAA results (based on the concentrations of V, Na, K, …

CHEMICAL CHARACTERIZATION OF ANCIENT LITURGICAL VESTMENT (CHASUBLE) BY ICP-OES

2016

Determination of trace elements in gluten-free food for celiac people by ICP-MS

2014

Abstract This paper is the first analytical approach to the study of twenty heavy metals in the gluten-free foods for celiac people. Only the ICP-MS technique was used. One of the advantages about the use of ICP-MS for this characterization is the high sensitivity that improved the limits of quantification levels for some elements that are present at low quantities in some samples. The concentration values of As, Ba, Cd, Co, Cr, Cu, Fe, Hg, Mn, Mo, Ni, Pb, Sb, Se, Sn, V and Zn in seventeen gluten-free food samples are reported. The highest arsenic and molybdenum levels were measured in Rice noodle from China (0.088 and 0.47 mg kg − 1 , respectively). The highest concentrations of some metal…